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The crystal structure of [WH2Cl2(PMe2Ph)4] and its dehydrochlorination to generate a reactive metal centre

โœ Scribed by Hangameh Dadkhah; Neimat Kashef; Raymond L. Richards; David L. Hughes; Armando J.L. Pombeiro


Book ID
103222311
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
231 KB
Volume
255
Category
Article
ISSN
0022-328X

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure