𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The crystal structure of the inclusion complex of cyclomaltoheptaose (β-cyclodextrin) with 4-tert-butylbenzoic acid

✍ Scribed by Aliki Rontoyianni; Irene M. Mavridis; Eugene Hadjoudis; Albert J.M. Duisenberg

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
829 KB
Volume
252
Category
Article
ISSN
0008-6215

No coin nor oath required. For personal study only.

✦ Synopsis

The crystal of the 1: 1 complex of cyclomaltoheptaose (p-cyclodextrin, PCD) with 4-tert-butylbenzoic acid is triclinic Pl with a = 18.244(3), b = 15.476(3), c = 15.417(2) A; (Y = 102.94(l), p = 113.08(l), y = 99.69(2)"; V = 3740(l) As; and Z = 2. The final R was determined to be 0.0932 for 8111 observed reflections (MoKa radiation). Two independent molecules of PCD form a dimer, via hydrogen bonds involving the O-3n atoms, that encloses two molecules of 4-tert-butylbenzoic acid. The guest molecules penetrate the pCD cavities to different depths. There are 26.8 water molecules, distributed over 30 sites, which form a dense water network surrounding the dimers.

* Atomic coordinates for this structure have been deposited with the Cambridge Crystallographic Data Centre. The coordinates may be obtained, on request, from the Director,

📜 SIMILAR VOLUMES

The crystal structure of the inclusion c
The crystal structure of the inclusion complex of cyclo-maltoheptaose (β-cyclodextrin) with 3,3-dimethylbutylamine
✍ Irene M. Mavridis; Eugene Hadjoudis; George Tsoucaris 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 680 KB

The crystal of the 1:1 complex of 3,3-dimethylbutylamine with cyclomaltoheptaose (beta CD, beta-cyclodextrin) is monoclinic C2 with a = 19.187(9), b = 24.56(1), c = 15.893(7) A, beta = 108.77(4) degrees, V = 7091 A3, and Z = 4. Two beta CD molecules, held together by intermolecular hydrogen bonds in

A side chain of diastereomeric iloprost
A side chain of diastereomeric iloprost protrudes from the cage in the complex with cyclomaltoheptaose (β-cyclodextrin): Crystal structure of (β-cyclodextrin)2 iloprost·20.5 H2O
✍ Thomas Steiner; Winfried Hinrichs; Wolfram Saenger; Georg-Alexander Hoyer 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 519 KB

A diastereomeric mixture of iloprost (16R: 16s = 55 :45) was co-crystallized with cyclomaltoheptaose (P-cyclodextrin, PCD) from aqueous solution as the complex (P-cyclodextrin),\*iloprost 020.5 H,O. The crystals are triclinic Pl; a = 15.474(10), b = 15.446(10), c = 18.081(10) A, (Y = 99.40(3); p = 1

Crystal structure of the 1:1 complex of
Crystal structure of the 1:1 complex of heptakis(2,3,6-tri-O-methyl)cyclomaltoheptaose (permethylated β-cyclodextrin) with ethyl laurate
✍ Dimitri Mentzafos; Irene M. Mavridis; Henk Schenk 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 714 KB

The crystal of the 1: 1 complex of ethyl laurate with heptakis(2,3,6-tri-0-methyl)cyclomaltoheptaose (ThI-@CD, permethyIated &cyclodextrin) is orthorombic, P&2,2,, with a = 14.796(Z), b m 22.444(6), c = 27.720@) A; V = 9~5(4) k3; and Z = 4. The macrocycles have a distorted ~nfo~ation due to the abse

Inclusion complexes of cyclomaltoheptaos
Inclusion complexes of cyclomaltoheptaose (β-cyclodextrin) and its methylated derivatives with the main components of the pheromone of the olive fruit fly
✍ Antigone Botsi; Konstantina Yannakopoulou; Eugene Hadjoudis 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 620 KB

The inclusion complexes of cyclomaltoheptaose (beta CD) and heptakis(2,3,6-tri-O-methyl)cyclomaltoheptaose (TM-beta CD) with the four major components of the pheromone of the olive fruit fly (Dacus oleae), namely 1,7-dioxaspiro[5.5]undecane, (-)-alpha-pinene, nonanal, and ethyl dodecanoate, and the