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The crystal structure of dibenzoyl peroxide and the dihedral angle in covalent peroxides

✍ Scribed by Sax, M. ;McMullan, R. K.

Book ID: 114520353
Publisher: International Union of Crystallography
Year: 1967
Tongue: English
Weight: 844 KB
Volume: 22
Category: Article
ISSN: 0365-110X
DOI: 10.1107/s0365110x67000477

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A t3C isotopic effect wasdetected in the triplet sensitized photolysis of dibenzoyl peroxide. Analysis of 13C NXR spectra shows that the amount of 13C in position 1 of phenyl benzoate, the cage product, increases by 23 f 5% in comparison with natural abundance. The observed isotopic effect considera