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The crystal structure of Ba5In3F19: a new structural type in fluoride crystal chemistry

✍ Scribed by A. De Kozak; N. Dupont; P. Gredin; D. Riou


Book ID
118618381
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
663 KB
Volume
1
Category
Article
ISSN
1293-2558

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Ba 2 CuAlF 9 is monoclinic: a = 5.374(2) A Ê , b = 7.312(2) A Ê , c = 9.371(3) A Ê , b = 90.20(1)°, Z = 2, space group P2 1 /c (n°14). The crystal structure was solved from X-ray single crystal data using 1071 unique reflections (900 with F o /r(F o ) > 4, R factor = 0.075). It is built up from infi

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Ba 2 Cu 2 AlF 11 is trigonal: a = 7.301(1) A Ê , c = 14.145(2) A Ê , c = 120°, Z = 3. The crystal structure was solved in the space group P3 2 (n°145), from X-ray single crystal data using 2675 unique reflections (2476 with F/r(F) > 4). It consists in a complex tridimensional arrangement of copperfl