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The crystal and molecular structure of sodium μ-triethylenetetraaminehexaacetatodi[oxo-vanadium(IV)] decahydrate, Na2[(VO)2TTHA].10H2O

✍ Scribed by Fallon, G. D. ;Gatehouse, B. M.


Book ID
117859934
Publisher
International Union of Crystallography
Year
1976
Weight
549 KB
Volume
32
Category
Article
ISSN
0567-7408

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Preparation, characterization, crystal a
✍ Giorgio Anderegg; Edgar Müller; Kurt Zollinger; Hans-Beat Bürgi 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 330 KB

The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined