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The crystal and molecular structure of cis-dichloro[(R)-α-methylbenzylamine] [(S)-1,2,2-trimethylpropyl (R)-vinyl ether]platinum(II)

✍ Scribed by Sartori, F. ;Leoni, L.

Book ID
117859941
Publisher
International Union of Crystallography
Year
1976
Weight
630 KB
Volume
32
Category
Article
ISSN
0567-7408

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Chiral platinum(II) complexes. Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl2((R,R)-CHIRAPHOS)]
✍ Maria H Johansson; Torsten Malmström; Ola F Wendt 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 120 KB

The reaction between trans-PtPhCl(SMe 2 ) 2 and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P2 1 with a=12.875(3), b=18.012(4), c= 13.864(3) A , , i = 109.71(3)°and Z =4. In CDCl 3 1 reacts with Ph 2 P(C 6 H 4 )CH 2 N(Me)(COEt) to give c