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The crystal and molecular structure of cis-4,6-dimethyl-2-oxo-2-triphenylmethyl-1,3,2-dioxaphosphorinan

✍ Scribed by Drew, M. G. B. ;Rodgers, J.

Book ID: 117857698
Publisher: International Union of Crystallography
Year: 1972
Weight: 638 KB
Volume: 28
Category: Article
ISSN: 0567-7408
DOI: 10.1107/s0567740872003413

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The crystal and molecular structures of a pair of diastereomeric 2-diphenylthiophosphinoylcis-(4,6-dimethyl)-1,3-dithianes 2 have been determined by the X-ray method. The differences in corresponding bond distances in cis-2 and trans-2 are discussed in context of the anomeric effect operating in thi