The rate coefficients for the removal of C1 atoms by reaction with three HCFCs, CF3CHC12 (HCFC-123), CF3CHFCl (HCFC-124), and CH3CFC12 (HCFC 141b), were measured as a function of temperature between 276 and 397 K. CH3CF2C1 (HCFC-142b) was studied only a t 298 K. The Arrhenius expressions obtained ar
The correlation of molecular rotational and translational kinetic energy in liquid CH2Cl2 and CHCl3
β Scribed by M.W. Evans; M. Ferrario
- Publisher
- Elsevier Science
- Year
- 1982
- Weight
- 209 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0378-4487
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## Abstract The rate coefficients for the reactions of Cl atoms with CH~3~Br, (__k__~1~) and CH~2~Br~2~, (__k__~2~) were measured as functions of temperature by generating Cl atoms via 308 nm laser photolysis of Cl~2~ and measuring their temporal profiles via resonance fluorescence detection. The m