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The correlation of core replacement energies with nonbonding s electron density

✍ Scribed by William L. Jolly; Christina Gin; David B. Adams

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
456 KB
Volume
46
Category
Article
ISSN
0009-2614

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✦ Synopsis

IicccivzJ 18 NovcmSer 1476

Core replacement energies are calcu!atcd for nitrogen and oxygen III various gaseous cations from accurate core binding encrgres and thermodyrwnic data. Thr vducs for a given clement differ in some cases by much more than the experimental errors. These chemical shifts in mre rcpkcement CncrbT wn be rationalized by rccognizmg that they ;ue equal to the shifts in the energy of transferring ZIR electron from ;I core Jevci to a nucleus. As expected, relativcIy endothermic core replacement energies arc found for atoms which hale a hgh density oi nonbonding valence s electrons.

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