𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The correction of rate data for the effects of internal temperature change

✍ Scribed by T. Boddington; P. Gray; B. J. Tyler

Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
640 KB
Volume
6
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The effect of reactant self‐heating or cooling upon rate data is considered, and three approaches to the problem of obtaining valid kinetic parameters are described in detail. A comparison of these approaches emphasises the need to assess and allow for thermal effects during the initial planning of kinetic experiments if satisfactory results are to be acquired. An integrated rate expression is given for use with nonisothermal data, and is used to provide correction factors for rate constants which have been derived without allowance for thermal effects.

πŸ“œ SIMILAR VOLUMES

The correction of rate data for the effe
The correction of rate data for the effects of internal temperature change
✍ T. Boddington; P. Gray; B. J. Tyler πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 34 KB

The corrections of rate data for the effects of internal temperature change are as follows: page 534, line 2 should read, "fC sincef, = ( j + 3 ) / ( j + 7), taking the critical dimensionless temperature gradient. . ."; page 534, line 5 should read, ". . . cylinder this method gives 11 l ] j = 2.729

Potentiostatic response of passive metal
Potentiostatic response of passive metals to the rate of temperature change
✍ T. Ishikawa; G. Okamoto πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 English βš– 696 KB

The effect of temperature on the steady anodic current of passive stainless steel in sulphuric acid solution containing no oxidizing agent was investigated in the temperature region below 100Β°C by raising the temperature in three different ways. The temperature dependence of the anodic current appea