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The copper-catalysed oxidation of ascorbic acid by dioxygen. Part 4. The effect of chloride ions on the kinetics and mechanism

✍ Scribed by Jameson, Reginald F.; Blackburn, Ninian J.


Book ID
126594305
Publisher
The Royal Society of Chemistry
Year
1982
Tongue
English
Weight
528 KB
Volume
1
Category
Article
ISSN
1472-7773

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## Abstract The copper‐catalyzed oxidation of ascorbic acid (AscH~2~) has been studied with a __Clark__ electrode in aqueous MeCN. Cu^I^ or Cu^II^ may be equally used as the source of metal ion, without influence on the rate law. At sufficiently high [MeCN], the rate of the overall reaction is esse