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The Cope rearrangement in theoretical retrospect

โœ Scribed by Viktor N. Staroverov; Ernest R. Davidson

Book ID
114141625
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
144 KB
Volume
573
Category
Article
ISSN
0166-1280

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๐Ÿ“œ SIMILAR VOLUMES

Theoretical analysis of the Cope rearran
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The reaction mechanisms via the transition states of a loose chair, a loose boat, and a Dewar type for the Cope rearrangement of 1,5-hexadiene have been studied by a CiLC-IRC analysis on the basis of a complete active space self-consistent field (CASSCF) molecular orbital (MO) method. The CiLC-IRC a

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## An aromatic oxy-Cope rearrangement can be achieved under anionic conditions (KH f HMPAl in Zow yield with a nuphthalene ring but not a phenyt. We have recently measured the activation parameters for an aromatic Cope rearrangement,l and these sug,oest that rearrangement of 4-phenyl-1-butene wou