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The coordination state and valence state of selected transition metal ions in SiO2–B2O3 xerogels

✍ Scribed by Andrzej M. Kłonkowski; Dominika Dunajska; Mariusz Biczkowski; Anna Jankowska-Frydel


Book ID
117145915
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
255 KB
Volume
311
Category
Article
ISSN
0022-3093

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O-vacancies in transition metal (TM) oxi
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Removal of neutral O-atoms from a transition metal (TM) oxide results in two electrons residing within the vacated site. Two-electron multiplet theory has been used to develop a d 2 equivalent model. When applied to tetragonal HfO 2 , the two electrons of neutral vacancy in the d 2 equivalent limit