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The coordination chemistry of molybdenum and tungsten. Part XIV. Dioxomolybdenum(VI) complexes of bidentate, tridentate, and tetradentate Schiff bases containing oxygen, nitrogen and sulphur donors

✍ Scribed by W.E. Hill; N. Atabay; C.A. McAuliffe; F.P. McCullough; S.M. Razzoki


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
684 KB
Volume
35
Category
Article
ISSN
0020-1693

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✦ Synopsis


A hzrge number of bidentate, tridentate, and tetmdentate Schiff base ligands containing oxygen, nitrogen, and sulphur donor atoms have been complexed to the cis-MoOz moie~. The structures of the resulting complexes are postulated on the basis of i&red and proton n.m.r. arguments previously developed by Yamada.

In the case of the complexes of the tetradentate ligands, the nature of the backbone between the imine groups determines which cis isomer is found. l-