The Coordination behavior of acyclic phoshites; a UV photoelectron spectroscopic study

✍ Scribed by A.H. Cowley; M. Lattman; R.A. Montag; J.G. Verkade

• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 176 KB
• Volume: 25
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)95682-2

✦ Synopsis

Phosphite

esters are employed extensively as ligands and, as such, are of great importance to the coordination chemist [l] .

In a previous publication [2] the UV photoelectron spectrum (UPS) of the simplest phosphite, (CH,O),P, was interpreted by analogy with that of [(CH&N] 3P. Like the latter compound, (CH30)3P exhibits four bands, II-I4 (Figure l), at low ionization energy (IE). Assuming a C, skeletal symmetry KH,Ol,P [J, nJee) 1 , u&a I , 1 , , , , , ,