The cooperative Jahn-Teller distorted structure of RbCuCl3
β Scribed by W.J. Crama
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 327 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-4596
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π SIMILAR VOLUMES
Prominent progressions of non-toti3i& wmmctric modes majr ensue in non-iinear mokcules in electronic transitions in-% alvk~~ degenerate states in the absence of Jahn-Teller distortions. In the presence of Jabn-Tel.kr interzctions prominent non-Jahn-Teller progreesions may result Jahn-Teller distorti
The electronic structure and spectroscopy of C~-o is examined using the intermediate neglect of differential overlap (INDO) model. The ground state of the ion distorts from Ih symmetry to either Dsd, D3d or D2h symmetry. The present study reveals that the Dsd structure is the equilibrium structure w