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The Conversion of Unsaturated 1,4-Diketones into Furans and Hydroxyfuranones

✍ Scribed by Lutz, Robert E.; McGinn, C. Edward

Book ID
127234862
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
424 KB
Volume
64
Category
Article
ISSN
0002-7863

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The Conversion of Furans into Phosphinin
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## Abstract The [4+2] cycloadducts between furan compounds and a methylenechlorophosphane pentacarbonyltungsten complex are converted into the corresponding 2‐hydroxy‐ or 2‐bromophosphinine complexes by treatment with BBr~3~ and triethylamine. The X‐ray crystal structure of the parent 2‐phosphaphen