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The conversion of methylenomycin A to natural botryodiplodin and their absolute configurations

✍ Scribed by Kiyoshi Sakai; Shigeo Amemiya; Kenji Inoue; Koichi Kojima

Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
218 KB
Volume
20
Category
Article
ISSN
0040-4039

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Both the enantiomers of sclerosporin 1 and sclerosporal 2 were synthesized from (-)carvone. (4R, 9R, lOR)-(+)-Sclerosporin and (4R, 9R, lOR)-(-)-sclerosporal were identified as natural enantiomers by bio-assay and by the CD-spectral comparison. Sclerosporin 1, the main sporogenic substance isolated