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The Conversion of 3-Hydroxy-6-heptenoic Acids into Bicyclo[3.2.0]hept-3-en-6-ones

โœ Scribed by Marotta, Emanuela; Medici, Massimo; Righi, Paolo; Rosini, Goffredo

Book ID
126223984
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
287 KB
Volume
59
Category
Article
ISSN
0022-3263

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Pure enantiomers of bicyclo[3.2.0]hept-3
Pure enantiomers of bicyclo[3.2.0]hept-3-en-6-ones and bicyclo[3.2.0]hept-3-en-6-endo-ols: Resolution, absolute configuration and optical properties
โœ Emanuela Marotta; Ilaria Pagani; Paolo Righi; Goffredo Rosini; Valerio Bertolasi ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 596 KB

Single crystal X-ray diffraction analysis of compounds A, B and, C helped us to assign the absolute configurations of the enantiomers of the bicyclo[3.2.0]hept-3-en-6-endo-ols 4-6. These bicyclic alcohols were easily obtained by: (i) stereoselective reductions of the bicyclo[3.2.0]hept-3-en-6-ones 1