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The contribution of vibration—phonon interaction to the vibrational line-shape of diatomics in noble gas matrices

✍ Scribed by Horia Metiu; Gregory E. Korzeniewski; Daniel Hone


Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
616 KB
Volume
58
Category
Article
ISSN
0009-2614

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✦ Synopsis


We examine the vibrational line-shape of an anharmonic, one-dimensional model of Co in argon_ The width thw~ obtained is too small and is linearly dependent on temperature below 2C!K. The lattice-induced shift has the wrong sign-and temperature dependence_ We conclude that hbrations must he important.