The construction of the substituted c/d ring system of delphinine-type alkaloids
β Scribed by K. Wiesner; T.Y.R. Tsai; K. Huber; S. Bolton
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 164 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
One phase of any successful totally synthetic approach to the construction of the diterpenoid alkaloids atisine (l)l and garryfoline (2)1'2 must be the elaboration of the C/D bicyclic ring system. While a method for the construction of such ring systems would be premature without the availability of
A&mrcc The first consrmctionof theA,B,C-ringsystemhavingall of the naturataubstituenta in ciguatoxin wasachievedfromB-glucose. O 1997EkevierScienceLtd. Ciguatoxitt 1 was isolated as the principal toxin causing ciguatera from moray eel Garnno thorax javanicur.The structureof 1 determined by Yasumoto