Regioselective Addition of Trimethylsily
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Igor S. Kruchok; Igor I. Gerus; Valery P. Kukhar
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Article
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2000
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Elsevier Science
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French
⚖ 118 KB
AbstractÐThe 1,2-and 1.4-addition reactions of trimethylsilyl cyanide to alkyl vinyl ketones were studied. Regioselectivity of this reaction depends on the structure of alkyl vinyl ketones, the reaction temperature and the nature of catalyst. The presence of alkoxy group in b-position of a,b-enone i