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The congruence of the adsorption isotherm and the model of the double layer new results regarding ethyl bromide

✍ Scribed by Sergio Trasatti; Giovanna Olivieri


Publisher
Elsevier Science
Year
1970
Weight
151 KB
Volume
27
Category
Article
ISSN
0022-0728

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✦ Synopsis


The problem of the correct choice of the electrical variable for the description of the adsorption of organic substances on electrodes has been recently discussed very widely 1-4 . No consensus of opinion has been so far achieved.

Behind the choice of the electrical variable there is the assumption of a well defined model for the adsorption layer. I f q M, the charge on the metal, is used as suggested by Parsons s , the potential is a linear function of the coverage:


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Adsorption of surfactants and the struct
✍ I.R. Miller πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 English βš– 969 KB

Differential capacitance of the electrical double layer of the mercury surface in contact with salt solutions containing different surfactants at various concentrations was measured. The potential of the desorption maximum (dl?/dE)B,fl.,t. cone. = maximum, which is always nearer to the electrocapill