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The Conformational Preference of the Nonbonding Electron Pair in Piperidine

✍ Scribed by Lambert, Joseph B.; Keske, Robert G.


Book ID
121426974
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
413 KB
Volume
88
Category
Article
ISSN
0002-7863

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Steric manipulation of the lone pair in
✍ Joseph B. Lambert; David S. Bailey; Barbara F. Michel πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 French βš– 229 KB

The remarkable preference of single-atom substituents for the axial position in certain molecules of the structure 11s2 was first satisfactorily explained by Allinger, et al.3 Their --Ia Ie Ha IIe analysis showed that the interactions in Ia between the axial proton on X and the 3,5-axial protons are