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The conformational and thermodynamic properties of poly-α-methylstyrene in various solvents

✍ Scribed by V.Ye. Eskin; T.N. Nekrasova; U.B. Zhurayev; A.F. Podol'skii; A.A. Taran

Book ID
118965472
Publisher
Elsevier Science
Year
1977
Weight
545 KB
Volume
19
Category
Article
ISSN
0032-3950

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On connection between conformational and
On connection between conformational and thermodynamic properties of poly-2,4-dimethylstyrene in various solvents
✍ V.E. Eskin; T.N. Nekrasova; U. Juraev 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 323 KB

The unperturbed chain dimensions K, of polydimethylstyrene (PDMS) in 12 solvents were determined b~ the Stockmayer-Fixman procedure. It was found that the value of K, decreased monotonously with increasing solvent power (i.e. with increasing the exponent a in the relation [r/] = K,I'd"l The unpertu