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The conformation of trimethylene sulphite

✍ Scribed by Gordon Wood; M. Miskow

Book ID
104211795
Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
176 KB
Volume
7
Category
Article
ISSN
0040-4039

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✍ Hannu Nikander; Veli-Matti Mukkala; Timo Nurmi; Kalevi Pihlaja 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 453 KB

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Ab initio calculations, in the frame of MO theory, were carried out on both most stable (chair) conformers of trimethylene cyclic sulfite. Optimized geometries derived at the HF/6-31G\* level reveal that both conformers possess a rigid chair conformation with the S=O group located either axially (co