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The Conformation of Medium-Sized Organosilicon Heterocycles: First evidence for the existence of a boat-boat conformation in a 12H-dibenzo[d,g][1,3,2]dioxasilocin

✍ Scribed by Hermann Fuhrer; Hansrudolf Meier; Günther Rist; Stephen D. Pastor; Sai P. Shum; Frank H. Clarke


Publisher
John Wiley and Sons
Year
1993
Tongue
German
Weight
268 KB
Volume
76
Category
Article
ISSN
0018-019X

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✦ Synopsis


For a review of recent activity, see [l].

For other ref., see [3].

For a review on methods to determine thermodynamic parameters by dynamic NMR, see [5].


📜 SIMILAR VOLUMES


Conformational Studies of Some t(4)-Acet
✍ K. Pandiarajan; A. Manimekalai; N. Kalaiselvi 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 368 KB 👁 2 views

The NOESY spectrum and vicinal coupling constants of t(4)-acetoxy-3,3-dimethyl-r(2),c(6)-diphenyl-Nacetylpiperidine suggest that the compound adopts a chair conformation with axial phenyl groups. The vicinal coupling constants of t(4)-acetoxy-r(2),c(6)-diphenyl-N-acetylpiperidine could be accounted