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The conformation of cis,cis -cyclodeca-3,8-diene-1,6-dione

✍ Scribed by Carrell, Horace L.; Roberts, Bryan W.; Donohue, Jerry.; Vollmer, John J.

Book ID: 127192206
Publisher: American Chemical Society
Year: 1968
Tongue: English
Weight: 263 KB
Volume: 90
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01021a035

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The transannular photocyclization of the cis,cis-cyclodecs-1,6+lienes to the tricyolo 5.3.0.02p6 --C 3 decane (1) may be explained due to the proximity in space of the two double bonds in the ~~hamnocks conformation I (2). Hence, in an intramolecular photocyclization of the isomeric trans,trans,cycl