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The conformation of 5-oxocanone evidence from 251 MHz 1H and 63 MHz 13C NMR

✍ Scribed by F.A.L. Anet; Peter J. Degen

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
161 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Some time ago, Leonard, Milligan, and Brown' tentatively assigned a boat-boat conformation (I bb ) to 5-oxocanone (l-oxacyclooctan-5-one)(I), a compound vfth a potential transannular interaction of the ether oxygen with the carbonyl group. However, recent work has shown that simple

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