✦ LIBER ✦

The configurations of (−)-2,3,3-trimethyl-2-hydroxybutanoic acid, Me3CC(Me)(OH)CO2H, (−)-3,3,4-trimethyl-3-hydroxy-1-pentyne and (−)-3-t-butyl-3-methyl-1-chloroallene

✍ Scribed by Ernest L. Eliel; Joseph E. Lynch; William R. Kenan Jr.

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 361 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96632-2

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✦ Synopsis

The configurations of the title compounds are reassigned, based on stereoselective syntheses of the hydroxyacid and corresponding glycol and application of Cram's, Prelog's and Sharpless' rules.

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