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THE CONFIGURATION OF Zr(C 2 O 4 ) 4-4 AND THE STEREOCHEMISTRY OF DISCRETE EIGHT-COORDINATION 1

โœ Scribed by Hoard, J. L.; Glen, G. L.; Silverton, J. V.


Book ID
127299359
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
394 KB
Volume
83
Category
Article
ISSN
0002-7863

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Coordination Chemistry of [Nb2(S2)2]4+ C
โœ M. Sokolov; A. Virovets; W. Clegg ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 151 KB ๐Ÿ‘ 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4ยฑ were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space