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The conductivity of pyrrolidinium and sulfonylimide-based ionic liquids: A combined experimental and computational study

โœ Scribed by Patrik Johansson; Leif Erik Fast; Aleksandar Matic; Giovanni B. Appetecchi; Stefano Passerini


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
211 KB
Volume
195
Category
Article
ISSN
0378-7753

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โœฆ Synopsis


Ionic conductivity is a fundamental property of ionic liquids with its origin and exact nature under debate. Using a specially selected system of pyrrolidinium cations (PYR 1x , x = 3,4) and sulfonylimide anions (FSI, TFSI, BETI, and IM14)-based ionic liquids we observe a simple and accurate connection between ab initio computed cation and anion volumes and measured molar ionic conductivities.


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