The condensation reaction between isocyanates and carboxylic acids. A practical synthesis of substituted amides and anilides.
β Scribed by Ian S. Blagbrough; Neil E. Mackenzie; Claudio Ortiz; A.Ian Scott
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 209 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Using BAC-MP4 potential-surface parameters, supplemented by an MP2 normal-mode analysis at one transition state, and statistical theoretical methods, we have computed thermal rate coefficients for the reactions, (1) Over the entire temperature range considered, 300 K < T < 3300 K, reaction (2) is
## Abstract The convenient methods for the synthesis of new monoβ and bisorganophosphorus substituted amides of unsaturated carboxylic acids with PCHNC(O) and antioxidant fragments, starting from Arbuzov reaction of the highly reactive adducts of corresponding imines and acyl chlorides with trimeth