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The Condensation of Acetophenone with Itself in the Presence of Lewis Acids 1

✍ Scribed by Elderfield, Robert C.; King, Te Piao

Book ID
118144632
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
387 KB
Volume
76
Category
Article
ISSN
0002-7863

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## Abstract __Lewis__ acids catalyze teh condensation of methyl pyruvate and l‐naphtol to give menthyl 2‐hydroxy‐2‐(l‐hydroxy‐2‐naphtyl)propionate in a ratio of up 96:4 in favor of the levorotatory diastereoisomer. Epimerization, at 25Β°C for five days, occurs on benzylic carbon atom to give a 30:70