✦ LIBER ✦

The concerted cycloaddition of cyclooctatetraene and MTAD; a bis-pericyclic process

✍ Scribed by Hervor Isaksen; James P. Snyder

Book ID: 104243898
Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 263 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92783-2

No coin nor oath required. For personal study only.

✦ Synopsis

Cyclooctatetraene

(COT, 1, is reluctant to participate in cycloaddition reactions leading to a Diels-Alder type product. Ordinarily the tetraene delivers the analog of the tetracyclic adduct 3 via its valence tautomer, bicyclo(4.2.0)-octatriene.

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