✦ LIBER ✦

The concept of statistical molecular association and its application to reaction kinetics and chemical equilibria

✍ Scribed by Prof. Dr.-Ing. Wolfgang Gestrich

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 731 KB
Volume: 16
Category: Article
ISSN: 0930-7516
DOI: 10.1002/ceat.270160402

No coin nor oath required. For personal study only.

✦ Synopsis

Dedicated to Professor Dr. Horst Langemann on the occasion of his 65th birthday

A simple statistical theory of molecular association has been developed, taking into account only the probability of residence of one or more molecules in an association volume. The result is a one parameter model which may be applied successfully to reaction kinetics and chemical equilibria of associated compounds. General concentration time profiles are presented and limiting cases discussed. Usefulness of the principle is demonstrated on experimental results.

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