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The computational and experimental investigations of photophysical and spectroscopic properties of BF2 dipyrromethene complexes

โœ Scribed by Valiev, R.R.; Sinelnikov, A.N.; Aksenova, Y.V.; Kuznetsova, R.T.; Berezin, M.B.; Semeikin, A.S.; Cherepanov, V.N.


Book ID
120928836
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
866 KB
Volume
117
Category
Article
ISSN
1386-1425

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The 2-ketopyrrole complexes 3 and 4 were isolated as minor products in syntheses of the corresponding 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY ยฎ ) dyes 1 and 2. Compounds 4 were shown to be highly fluorescent having emissions between 504 and 544 nm with quantum yields between 0.52 and 0.89