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The “Coloring Problem” in Solids: How It Affects Structure, Composition and Properties

✍ Scribed by Gordon J. Miller


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
377 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis


The "coloring problem," as applied to the field of solid state chemistry, addresses the issues of structural preference as well as the distribution of different elements within a given structure. Both the connectivity and arrangement of elements in a solid affect physical and chemical properties, so a clear understanding of the forces controlling how elements will arrange themselves in a solid state structure creates the ability MICROREVIEWS: This feature introduces the readers to the authors' research through a concise overview of the selected topic. Reference to important work from others in the field is included.


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Complete analyses of the proton and carbon chemical-shift assignments of D-mannurono-y-lactone (1) have been achieved by 1D and 2D NMR spectral measurements. At equilibrium, the anomeric LY and p forms were present in the ratio of 34:66 in D,O and 72:28 in Me,SO-d,. The solution data indicated tha