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The Cobalt-Catalyzed Alternating Copolymerization of Epoxides and Carbon Monoxide: A Novel Approach to Polyesters

✍ Scribed by Allmendinger, Markus; Eberhardt, Robert; Luinstra, Gerrit; Rieger, Bernhard


Book ID
121387447
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
81 KB
Volume
124
Category
Article
ISSN
0002-7863

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## Abstract The cobalt‐catalyzed alternating copolymerization of epoxides and CO is a novel, direct approach to aliphatic polyesters, such as poly(hydroxybutyrate) (PHB). This reaction was found to be catalyzed by Ph~3~Si[Co(CO)~4~] (4) and pyridine affording in a first step the stable mono‐inserti