The CO-catalyzed conversion of H2S to H2 + sulfur part 2. The thermal decomposition of COS
β Scribed by Farhad Faraji; Imre Safarik; Otto P. Strausz; Erdal Yildirim; Manuel E. Torres
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 689 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0008-4034
No coin nor oath required. For personal study only.
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A compacl algonlhm LS prcscntcd lo oblam the two4cctron mlegral dcrwatwe contrlbullon to MCSCT gradumts that avoads the story= of tllc integral dcnvatwcs or Lhc bnck-tmsformcd ~wa~lcctran dcm,ly matn\. The WC SCI-gndwnts are apphed to the opllmlzahon of the HlCO -Hz + CO transItIon structure at the
The kinetics of the reactions of H atoms with H2S and with COS were measured at 298' K in a flow system using mass-spectrometric detection. The rate constants were found to be 3.8 X 10-13 and 2.2 X lo-'\* cm3 part-' sec-l, respectively, with an estimated accuracy of 25y0. At high flow rates of HZS,