Bands of the following well-known systems were ob-In~aur. Ju\rus-l.leb$-Uni\~r\llrit. Gicswn, \Vcw Germ\_m) \_ served in absorption in the above experiments: free radical spectra have been obtained together with a spectrum which appears to correspond to that of the CNO free radical discussed above.
The CNO free radical and its isomerization in inert-gas matrices
β Scribed by V.E. Bondybey; J.H. English; C.W. Mathews; R.J. Contolini
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 487 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
200 mL) was acidified with 3 drops of 32% HCI and stirred for 15 min at 50Β°C (exclusion of light). After extraction with CH,CI,, the organic phase was dried (Na,SO,) and purified on silica gel (20 8). After removal of the solvent there remained 0.53 g (72%) of a crystalline product. For further puri
Ground-state vibrational frequencies of the matrix-isolated B 3 and A13 molecules have been observed. For A13, there also appears a progression of bands beginning at ~ 1800 cm-J, which is attributed to absorption to a low-lying electronic state.