THE CLEAVAGE OF DIETHYL α,α'-DIBROMO-ADIPATE BY DIETHYLAMINE
✍ Scribed by Fuson, Reynold C.
- Book ID
- 127167571
- Publisher
- American Chemical Society
- Year
- 1928
- Tongue
- English
- Weight
- 367 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
Ynolates have been synthesized via the thermally-inducedcleavage of ester dianions. The key intermediates, ester dianions, were generated from ~t -bromocarboxylic acid ester enolates via lithium halogen exchange, ot,~-Dibromocarboxylic acid ester also gives lithium amide free ynolates by addition of
Novel Synthesis of Ynolates via the Cleavage of Ester Dianions: α-Bromo and α,α-Dibromo Esters as Precursors. -Thermal cleavage of ester dianions generated from readily available α-bromo-and α,α-dibromo esters offers a new and convenient method to prepare lithium ynolates. The ynolates react with al