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The cleavage of a cluster carbonyl CO bond by trifluoromethanesulphonic anhydride

✍ Scribed by Philip J. Bailey

Book ID
107812089
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
189 KB
Volume
420
Category
Article
ISSN
0022-328X

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tic-Diols were oxidized with aqueous hydrogen peroxide in the presence of heteropolyacids to yield carboxylic acids as main products in good yields. Although the oxidation proceeded via cw-ketol or cu-diketone intermediates, another oxidation path such as direct C-C bond cleavage is suggested in the