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The Claisen rearrangement of iron (allyloxy)carbene complexes

โœ Scribed by Barrett, Anthony G. M.; Carpenter, Nancy E.

Book ID
121458513
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
267 KB
Volume
6
Category
Article
ISSN
0276-7333

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โœ M.J. Sleeman; G.V. Meehan ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

A number of ally1 allenyl ethers (1) have been synthesised and shown to undergo the Claisen rearrangement. The kinetics of rearrangement of (lb) together with stereochemical data obtained, is consistent with a concerted mechanism for these rearrangements. A number of variants of the Claisen rearra