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The chromatographic processes for preparation of isotope-free hydrogen

โœ Scribed by Z.W. Wei


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
578 KB
Volume
12
Category
Article
ISSN
0360-3199

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Secondary hydrogen isotope effect for th
โœ Richard W. Henderson; William A. Pryor ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 279 KB

Secondary kinetic isotope effects occur in radical additions to deuterated olefins. Substitution of a deuterium at a carbon undergoing an sp2 to sp3 hybridization-change during reaction, Cg in eq. ( I ) , leads to an The effect at a carbon going from a n olefinic to a radical center, C, in eq. (I),