Secondary hydrogen isotope effect for th
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Richard W. Henderson; William A. Pryor
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Article
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1972
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John Wiley and Sons
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English
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Secondary kinetic isotope effects occur in radical additions to deuterated olefins. Substitution of a deuterium at a carbon undergoing an sp2 to sp3 hybridization-change during reaction, Cg in eq. ( I ) , leads to an The effect at a carbon going from a n olefinic to a radical center, C, in eq. (I),