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The (Chloromethyl)dihalosilanes X2HSiCH2Cl (X = F, Cl, Br, I): Synthesis, Multinuclear NMR Spectroscopy and Rotational Isomerism Examined by Raman Spectroscopy

✍ Scribed by Karl Hassler; Reinhard Hummeltenberg; Günter Tekautz


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
132 KB
Volume
2004
Category
Article
ISSN
1434-1948

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The Raman vibrational spectra of the heptamethyltrisilanes with X = H, F, Cl, Br, XMe 2 SiSiMe 2 SiMe 3 , C 6 H 5 and unambiguously prove the presence of two rotamers, anti and gauche, in the liquid state. With variable-OCH 3 , temperature Raman vibrational spectroscopy, enthalpy di †erences between