✦ LIBER ✦

The chloro-substituent as a steering group: A comparative study of non-bonded interactions and hydrogen bonding in crystalline chloro-aromatics

✍ Scribed by Jagarlapudi A.R.P. Sarma; Gautam R. Desiraju

Book ID: 103026983
Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 399 KB
Volume: 117
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85227-1

No coin nor oath required. For personal study only.

✦ Synopsis

l3slinctive pallems of C.. C, CI._.CI and C...CI non-bonded short contacLs are oblained for 4 A short axis fi-structures and for nor&s~~ctures in a senes of polychlor~aromatics, phenols and anilines. The direclions of the shortest Cl _ _ _ Cl and C.--C contacts provide an insight mto the role or the chloro-subsliluenl as a skcring group in the crystal engineering of Although the hterature has been controversial with regard to the ongin and nature of Cl...Cl lnteractlons in orgamc molecular solids [l-3], there is little doubt that short mtermolecular Cl...Cl contacts, which may be aslow as 3.21 A [3]', are found widely in the structures of chloro-compounds, especrally polychloro-

📜 SIMILAR VOLUMES

Molecular orbital theory of the hydrogen

Molecular orbital theory of the hydrogen bond.: XVI. A comparative study of pyridine and the diazines as proton acceptors in ground and excited n → π* states

✍ Janet E. Del Bene 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 965 KB

A comparative study of the hydrogen-bond

A comparative study of the hydrogen-bonding patterns and prototropism in solid 2-thiocytosine (potential antileukemic agent) and cytosine, as studied by1H-14N NQDR and QTAIM/ DFT

✍ Jolanta N. Latosińska; Janez Seliger; Veselko Žagar; Dorota V. Burchardt 📂 Article 📅 2011 🏛 Springer-Verlag 🌐 English ⚖ 657 KB

NON-AQUEOUS TITRATIONS AS A TOOL IN THE

NON-AQUEOUS TITRATIONS AS A TOOL IN THE STUDY OF MOLECULAR RECOGNITION PHENOMENA. USES IN DISTINGUISHING HYDROGEN BONDING FROM PROTON TRANSFER, THE MEASUREMENT OF COMPLEX INDUCED pKa SHIFTS, AND THE ABILITY TO DISTINGUISH THE CATALYTIC ROLES OF GENERAL ACIDS AND BASES

✍ Christine L. Hannon; Dwayne A. Bell; Anne M. Kelly-Rowley; Larry A. Cabell; Eric 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 120 KB 👁 3 views

Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho