The effect of high boiling point solvent on the residual stress behaviors of semiflexible structure poly(4,4Π-oxydiphenylene pyromellitimide) (PMDA-ODA) and pseudo-rodlike poly(p-phenylene biphenyltetracarboximide) (BPDA-PDA) polyimide was investigated. As a solvent, a mixed solution of 20 wt % cycl
β¦ LIBER β¦
The Chiroptical Properties of a Thermally Annealed Film of Chiral Substituted Polyfluorene Depend on Film Thickness
β Scribed by M.R. Craig; P. Jonkheijm; S.C.J. Meskers; A.P.H.J. Schenning; E.W. Meijer
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 124 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0935-9648
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β¦ Synopsis
The degree of circular polarization in the absorption of light by a thermally annealed film of chirally substituted polyfluorene depends strongly on the film thickness. This indicates that the exceptionally high dissymmetry ratios observed for these films originate on a nanoscopic level and are related to the longβrange correlation in the polymer chain orientation. Circular polarizations (see Figure) of up to 50β% can be reached.
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