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The chiral pyrethroid cycloprothrin: Stereoisomer synthesis and separation and stereoselective insecticidal activity

✍ Scribed by Biao Jiang; Hua Wang; Qun-Mei Fu; Zhu-Yi Li


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
142 KB
Volume
20
Category
Article
ISSN
0899-0042

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The reaction of chiral 2-trifluoromethyl-1,3-oxazolidines with various silylated nucleophiles under Lewis acid activation provides a stereoselective route to functionalized a-trifluoromethylamines. This methodology was successfully applied to the diastereoselective synthesis of trifluoromethylated h