A kinetic investigation has been carried out on the reduction of some aromatic ketones (acetophenone, 1;2-methoxyacetophenone, 2; 3-methoxyacetophenone, 3; 4-methoxyacetophenone, \(4 ;\) and \(\alpha\)-tetralone, 5 ) by sodium borohydride in the presence of two cationic surfactants (cetyltrimethylam
The chemospecific reduction of aldehyde and ketone with sodium borohydride in the presence of thiol
β Scribed by Yuji Maki; Katsuo Kikuchi; Hiroshi Sugiyama; Shuichi Seto
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 115 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The rates for the reduction of ketones with sodium borohydride are interpreted in terms of two parameters, both derived from forceβfield calculations; __i.e.__ the strain difference between alcohol and ketone (Ξ strain) and the steric hindrance towards approach of the hydride R. Models
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v